|
|
(E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-omega-(methylsulfanyl)heptan-1-imine + H2O <=> (E)-omega-(methylsulfanyl)heptyl-thiohydroximate + L-seryl-glycine
|
4.4.1.M2
|
–
|
| |
MetaCyc:
RXN-11441
|
|
|
|
4-methylthioheptanaldoxime + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 1-(methylsulfanyl)-7-aci-nitroheptane + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11417
|
|
|
|
L-tetrahomomethionine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> H2O + CO2 + oxidized_[NADPH-hemoprotein_reductase] + 4-methylthioheptanaldoxime
|
1.14.14.42
homomethionine N-monooxygenase
|
–
|
| |
MetaCyc:
RXNQT-4311
|
|
|
|
1-(methylsulfanyl)-7-aci-nitroheptane + glutathione <=> (E)-1-(glutathion-S-yl)-N-hydroxy-omega-(methylsulfanyl)heptan-1-imine + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11425
|
|
|
|
6-methylthiohexylglucosinolate + O2 + NADPH + H+ <=> 6-methylsulfinylhexyl-glucosinolate + H2O + NADP+
|
1.14.13.237
aliphatic glucosinolate S-oxygenase
|
–
|
| |
MetaCyc:
RXNQT-4336
|
|
|
|
(E)-1-(glutathion-S-yl)-N-hydroxy-omega-(methylsulfanyl)heptan-1-imine + H2O <=> (E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-omega-(methylsulfanyl)heptan-1-imine + L-glutamate
|
3.4.19.16
glucosinolate gamma-glutamyl hydrolase
|
–
|
| |
MetaCyc:
RXN-11433
|
|
|
|
(E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-omega-(methylsulfanyl)heptan-1-imine + H2O <=> (E)-1-(L-cystein-S-yl)-N-hydroxy-omega-(methylsulfanyl)heptan-1-imine + glycine
|
3.4.13.23
cysteinylglycine-S-conjugate dipeptidase
|
–
|
| |
MetaCyc:
RXN-19592
|
|
|
|
(E)-1-(L-cystein-S-yl)-N-hydroxy-omega-(methylsulfanyl)heptan-1-imine + H2O <=> (E)-omega-(methylsulfanyl)heptyl-thiohydroximate + pyruvate + NH3
|
4.4.1.13
cysteine-S-conjugate beta-lyase
|
–
|
| |
MetaCyc:
RXNQT-4321
|
|
|
|
3''-phosphoadenylyl-sulfate + 6-(methylsulfanyl)hexyl-desulfoglucosinolate <=> adenosine_3,5''-bisphosphate + H+ + 6-methylthiohexylglucosinolate
|
2.8.2.38
aliphatic desulfoglucosinolate sulfotransferase
|
–
|
| |
MetaCyc:
RXNQT-4331
|
|
|
|
UDP-glucose + (E)-omega-(methylsulfanyl)heptyl-thiohydroximate <=> H+ + 6-(methylsulfanyl)hexyl-desulfoglucosinolate + UDP
|
2.4.1.195
N-hydroxythioamide S-beta-glucosyltransferase
|
–
|
| |
MetaCyc:
RXNQT-4326
|
|
